蔡正國(guó)教授 蔡正國(guó),1975年5月生,材料科學(xué)與工程學(xué)院,纖維材料改性國(guó)家重點(diǎn)實(shí)驗(yàn)室,教授。2011年回國(guó)前,在日本廣島大學(xué)任助理教授。 研究方向: 1、 配位聚合與大分子設(shè)計(jì); 2、 新型成纖高聚物設(shè)計(jì)、合成及應(yīng)用研究 主要研究成果 高性能聚烯烴材料開(kāi)發(fā)與性能研究 榮譽(yù)及獲獎(jiǎng)情況: 1、2006年度國(guó)家優(yōu)秀自費(fèi)留學(xué)生獎(jiǎng)學(xué)金 2、2010年度日本高分子研究獎(jiǎng)勵(lì)賞 近幾年承擔(dān)的項(xiàng)目: 1、國(guó)家自然科學(xué)基金面上項(xiàng)目(21174026),可共聚、可控立構(gòu)聚丙烯活性聚合催化劑研究,2012. 01-2015. 12,正在進(jìn)行,63萬(wàn)元,主持人 2、東華大學(xué)基本科研業(yè)務(wù)費(fèi)(追加)專項(xiàng)資金,降冰片烯為單體的耐熱性光學(xué)高分子材料研究,2011. 10-2012. 9,正在進(jìn)行,30萬(wàn)元,主持人 3、日本學(xué)術(shù)振興會(huì)青年學(xué)者海外派遣基金,乙烯與極性單體的共聚合,2010. 08-2011. 01,已完成,150萬(wàn)日元,主持人 4、日本國(guó)家科學(xué)研究費(fèi),環(huán)烯烴共聚物的精密合成,2008. 04-2011. 03, 已完成,1900萬(wàn)日元,項(xiàng)目負(fù)責(zé)人 近幾年發(fā)表的論著作 1、 Z. Cai, R. Harada, Y. Nakayama and Takeshi Shiono: Highly Active Living Random Copolymerization of Norbornene and 1-Alkene with ansa-Fluorenylamidodimethyltitanium Derivative: Substituent Effects on Fluorenyl ligand; Macromolecules 43[10], 4527-4531, (2010) 2、 Z. Cai, R. Y. Nakayama and Takeshi Shiono: Synthesis of Stereoblock Polypropylene by Change of Temperature in Living Polymerization; Macromole. Res. 18 [8], 737-741 (2010). 3、 Z. Cai, M. Oomagari, Y. Nakayama and T. Shiono: Highly Active Syndiospecific Living Polymerization of Higher 1-Alkene with ansa-Fluorenylamidodimethyltitanium Complex; Macromol. Rapid Commun. 30, 1812-1816 (2009) 4、 Z. Cai, M. Shinzawa, Y. Nakayama and Takeshi Shiono: Synthesis of Regioblock Polybutadiene with CoCl2-based Catalyst via Reversible Coordination of Lewis Base; Macromolecules 42[20], 7642-7643 (2009) 5、 Z. Cai, Y. Nakayama and T. Shiono: Facile Synthesis of Tailor-Made Stereoblock Polypropylenes via Successive Variation of Monomer; Macromolecules 41[17], 6596-6598 (2008) 6、 Z. Cai, Y. Nakayama and T. Shiono: Catalytic Synthesis of a Monodisperse Olefin Block Copolymer Using a Living Polymerization System; Macromol. Rapid Commun. 29, 525-529 (2008) 7、 Z. Cai, M. Shigemasa, Y. Nakayama and T. Shiono: Catalytic Synthesis of Monodisperse Polypropylene Using a Living Polymerization System with ansa-Fluorenylamidodimethyltitanium Based Catalysts; Macromolecules 39[19], 6321-6323 (2006) 8、 Z. Cai, Y. Nakayama and T. Shiono: Living Random Copolymerization of Propylene and Norbornene with ansa-Fluorenylamidodimethyltitanium Complex: Synthesis of Novel Syndiotactic Polypropylene-b-Poly(propylene-ran-norbornene); Macromolecules 39[6], 2031-2033 (2006) 9、 Z. Cai, T. Ikeda, M. Akita and T Shiono: Substituent Effect of tert-Butyl Group on Fluorenyl Ligand in Syndiospecific Living Polymerization of Propylene with ansa-Fluorenylamidodimethyltitanium Complex; Macromolecules 38[20], 8135-8139, (2005) 學(xué)術(shù)兼職: 日本化學(xué)會(huì)(CSJ)、日本高分子學(xué)會(huì)(SPSJ)、日本催化學(xué)會(huì)(CATSJ)以及美國(guó)化學(xué)學(xué)會(huì)(ACS)會(huì)員 聯(lián)系電話:67792453 EMAIL:caizg@dhu.edu.cn |